Ion beam oxidation of GaAs: The role of ion energy
O. Vancauwenberghe, N. Herbots. H. Manoharan,a) and M. Ahrens
Massachusetts Institute of Technology, Cambridge,
Maassachusetts 02139
J. Vac. Sci. Technot A 9 (3), May/Jun 1991, pp. 1035-1039
In this work, room temperature oxidation of GaAs was investigated using ion beam oxidation (mO). In lBO, an ion beam... more
In this work, room temperature oxidation of GaAs was investigated using ion beam oxidation (mO). In lBO, an ion beam is used to introduce oxygen athermally into the substrate, in this case GaAs. GaAs bonds are broken upon collision with the ions, making gallium and arsenic atoms readily available to react with the oxygen species. Ion beam oxidation of GaAs at room temperature was studied as a function ofoxygen ion energy between 500 and is keY. The ion beam oxidized GaAs was characterized in situ by Auger electron spectroscopy (AES) and ex situ with x-ray photoelectron spectroscopy (XPS) for accurate determination of the film chemical composition. Below 1 keY, a thin oxide film is formed: it is composed of Ga20 3 and AS20 3 with almost no metallic arsenic, and presents insulating properties.
As the ion energy increases, preferential sputtering of As and decomposition of AS203 increase and prevent formation of an
insulating film. No damage was detected by Rutherford backscattering spectrometry (RES) combined with ion channeling, in the substrate subjected to IBO below 1 keV.
Genesis of our discovery of ordered interphases of SiO2, a journalist's perspective
This article was written by a reporter for the Research Corporation Bulletin in 1999 after he interviewed me following a Research Opportunity Award in the amount of $25 k from the Research Corp. ASU and ARBOR matched the award with another $25k.
Dr. Herbots, Belgian-born, Ph.D. graduate in applied physics of Catholic University of Louvain and a microelectronics... more
Dr. Herbots, Belgian-born, Ph.D. graduate in applied physics of Catholic University of Louvain and a microelectronics specialist, made progress in the course of three years as an Oak Ridge Re- search Associate and four years as an MIT professor (1987-1991). At MIT she developed new methods for synthesizing thin film layers on chips at low temperatures, and for creating films that can’t be grown using thermal processes.
She joined Arizona State University in 1991, to further develop a novel invention she had made at MIT. Called Combined Ion and Molecular Beam Deposition or CIMD, it is a tech- nique for depositing materials on semiconductors that combines a so- phisticated evaporation system (molecular beam deposition) with an easily controlled ion beam.
But a life-threatening accident curtailed her research
After building a CIMD clean room at Arizona State University and getting research off to a good start, Nicole Herbot’s work, almost her life, came to an abrupt end in May 1994. This is where the history of her research in ordered nanophases of SiO2 on Si(100) began. She had to rebuild her scientific understanding of matter, interfaces, phase structures and nanophases after losing her short memory and developing "petit mal" (a milder form of epilepsy characterized by short or longer "absences" where the patient loses awareness of surroundings without loss of consciousness). The episodes increase with fatigue, mild illnesses and colds, to several a day. They result in post-"absences" exhaustion, typical of epilepsy, where the patient needs to sleep for a period of time concomittant with the duration of the absences to recover. The condition precludes driving.
The long hours spent on bed rest recovering from the petit mal absences gave her the time to reflect on the continuing mystery of SiO2/Si(100) extraordinary properties in microelectronics. This is how her "Tsunami" model of structural collapse as Si(100) crystals oxidizes into an amorphous film came to be, and a new concept to prevent structure loss and thus grow heteroepitaxial SiO2 on Si(100) was conceived, and led to several patents (2003, 2010), PhD theses and papers.
Analysis of native biological surfaces using a 100kV Massive Gold Cluster source
by Francisco A. Fernandez-Lima
Anal. Chem. 2011, 83, 8448–8453
Alkali halide clusters produced by fast ion impact
by Francisco A. Fernandez-Lima
Nucl. Instr. and Meth. in Phys. Res. B 273, 102–104, 2012.
On the Surface Mapping using Individual Cluster Impacts
by Francisco A. Fernandez-Lima
Nucl. Instr. and Meth. in Phys. Res. B B 273, 270–273, 2012.
Imaging of Cells and Tissues with Mass Spectrometry: Adding Chemical Information to Imaging
T.A. Zimmerman, E.B. Monroe, K.R. Tucker, S.S. Rubakhin, J.V. Sweedler, Methods Cell Biol. 89, 2008, 361-390.
Electronic sputtering analysis of astrophysical ices
by Francisco A. Fernandez-Lima
Earth, moon, and planets, 97, 311-329, 2005
Theoretical and Experimental Analysis of Ammonia Ionic Clusters Produced by 252Cf Fragment Impact on an NH3 Ice Target
by Francisco A. Fernandez-Lima
J. Phys. Chem. A, 110(33), 10018-10024, 2006
Characterization of Cn=2-16+ clusters produced by electronic sputtering
by Francisco A. Fernandez-Lima
Chem. Phys. Lett., 426, 351-356, 2006
Characterization of Nn=2-18+ clusters produced by 252Cf fission fragment impact on a N2 ice target
by Francisco A. Fernandez-Lima
Chem. Phys., 340, 127-133, 2007
Characterization of (NH3)n=1-6NH+ clusters produced by 252Cf impact onto a NH3 condensed target
by Francisco A. Fernandez-Lima
J. Phys. Chem. A, 111(34), 8302-8307, 2007
Characterization of Cn=2-16clusters produced by 337nm UV laser
by Francisco A. Fernandez-Lima
Chem. Phys. Lett., 445, 147-151, 2007
A theoretical and experimental study of positive and neutral LiF clusters produced by fast ion impact on a polycrystalline LiF target
by Francisco A. Fernandez-Lima
J. Phys. Chem. A, 113, 1813-1821, 2009
An experimental and theoretical description of the (NH3)n-1{NH3-H-H2O}+ cluster ions produced by fast ion bombardment
by Francisco A. Fernandez-Lima
Chem. Phys. Lett. 474(1-3), 185-189, 2009
A Theoretical and Experimental Study of Negative LiF Clusters Produced by Fast Ion Impact on a Polycrystalline LiF Target
by Francisco A. Fernandez-Lima
J. Phys. Chem. A, 113 (52), 15031–15040, 2009
Photon emission from massive projectile impacts on solids
by Francisco A. Fernandez-Lima
Surf. Interface Anal., 43 (1-2), 53–57, 2011
Photon, Electron and Secondary Ion Emission from Single C60 keV Impacts
by Francisco A. Fernandez-Lima
J. Phys. Chem. Lett., 1, 3510–3513, 2010
12 views

